Osmotic coefficients and activity coefficients of electrolytes in non-aqueous solvents

This collection was compiled during the preparation of the publication: Mazzini, V and Craig, V. S. J. Volcano Plots Emerge from a Sea of Nonaqueous Solvents: The Law of Matching Water Affinities Extends to All Solvents. ACS Central Science 2018 4 (8), 1056-1064. DOI: 10.1021/acscentsci.8b00348; and is also referred to in Virginia Mazzini's PhD Thesis (available for download at http://hdl.handle.net/1885/144595 ). This database is a collection of the published experimental data regarding the osmotic and activity coefficients of binary electrolyte solutions (mostly 1:1 electrolytes) in non-aqueous solvents. This database focuses on experimental data at 298.15 K, but additional temperatures are included if present in the original publication. For each electrolyte in each solvent, the database lists the osmotic and/or activity coefficient (depending on what the authors measured and calculated in the literature reference) at the indicated concentration and temperature. If the original authors had fitted the data with the Pitzer or Pitzer-Archer model in their publication, the fitting coefficients they obtained are included. The data in Bonner1969 were calculated using a cryoscopic constant for ethylene carbonate that is now out of date. Better to recalculate the osmotic and activity coefficients of the publication using an up-to date cryoscopic constant value. This database contains data on binary electrolyte solutions in the following solvents: 2-propanol (propan-2-ol), acetone (propan-2-one), N,N-dimethylacetamide, dimethyl carbonate, dimethoxyethane (1,2-dimethoxyethane), N,N-dimethylformamide (short DMF), dimethyl sulfoxide (short DMSO), ethylene carbonate (1,3-dioxolan-2-one), ethanol, acetonitrile, methanol, N-methylacetamide, N-methylformamide (short NMF), propylene carbonate (4-methyl-1,3-dioxolan-2-one), sulfolane (tetrahydrothiophene 1,1-dioxide). This database contains data on the following salts in non-aqueous solvents: tetrabutylammonium bromide, tetrabutylammonium chloride, tetrabutylammonium perchlorate, tetrabutylammonium iodide, cesium bromide, cesium chloride, cesium iodide, tetraethylammonium bromide, tetraethylammonium chloride, tetraethylammonium iodide, potassium bromide, potassium chloride, potassium perchlorate, potassium iodide, potassium nitrate, potassium acetate, potassium propionate, potassium thiocyanate, lithium bromide, lithium chloride, lithium perchlorate, lithium formate, lithium iodide, lithium nitrate, lithium acetate, lithium propionate, tetramethylguanidinium chloride, tetramethylguanidinium perchlorate, tetramethylammonium bromide, tetramethylammonium chloride, sodium bromide, sodium chloride, sodium perchlorate, sodium formate, sodium iodide, sodium nitrate, sodium acetate, sodium propionate, sodium thiocyanate, ammonium chloride, ammonium iodide, ammonium thiocyanate, tetrapentylammonium bromide, tetrapropylammonium bromide, tetrapropylammonium chloride, tetrapropylammonium iodide, rubidium perchlorate, rubidium iodide, zinc chloride, zinc iodide.
Type
Collection
Title
Osmotic coefficients and activity coefficients of electrolytes in non-aqueous solvents
Collection Type
Collection
Access Privileges
Colloid and Interfaces Group
DOI - Digital Object Identifier
10.25911/5c946ccad12e4
Metadata Language
English
Data Language
English
Brief Description
This is a collection of the published osmotic coefficients and/or activity coefficients data on non-aqueous electrolytes (mostly 1:1 electrolytes) at 298.15 K (data at additional temperatures is included if present in the original publication).
Full Description
This collection was compiled during the preparation of the publication: Mazzini, V and Craig, V. S. J. Volcano Plots Emerge from a Sea of Nonaqueous Solvents: The Law of Matching Water Affinities Extends to All Solvents. ACS Central Science 2018 4 (8), 1056-1064. DOI: 10.1021/acscentsci.8b00348; and is also referred to in Virginia Mazzini's PhD Thesis (available for download at http://hdl.handle.net/1885/144595 ). This database is a collection of the published experimental data regarding the osmotic and activity coefficients of binary electrolyte solutions (mostly 1:1 electrolytes) in non-aqueous solvents. This database focuses on experimental data at 298.15 K, but additional temperatures are included if present in the original publication. For each electrolyte in each solvent, the database lists the osmotic and/or activity coefficient (depending on what the authors measured and calculated in the literature reference) at the indicated concentration and temperature. If the original authors had fitted the data with the Pitzer or Pitzer-Archer model in their publication, the fitting coefficients they obtained are included. The data in Bonner1969 were calculated using a cryoscopic constant for ethylene carbonate that is now out of date. Better to recalculate the osmotic and activity coefficients of the publication using an up-to date cryoscopic constant value. This database contains data on binary electrolyte solutions in the following solvents: 2-propanol (propan-2-ol), acetone (propan-2-one), N,N-dimethylacetamide, dimethyl carbonate, dimethoxyethane (1,2-dimethoxyethane), N,N-dimethylformamide (short DMF), dimethyl sulfoxide (short DMSO), ethylene carbonate (1,3-dioxolan-2-one), ethanol, acetonitrile, methanol, N-methylacetamide, N-methylformamide (short NMF), propylene carbonate (4-methyl-1,3-dioxolan-2-one), sulfolane (tetrahydrothiophene 1,1-dioxide). This database contains data on the following salts in non-aqueous solvents: tetrabutylammonium bromide, tetrabutylammonium chloride, tetrabutylammonium perchlorate, tetrabutylammonium iodide, cesium bromide, cesium chloride, cesium iodide, tetraethylammonium bromide, tetraethylammonium chloride, tetraethylammonium iodide, potassium bromide, potassium chloride, potassium perchlorate, potassium iodide, potassium nitrate, potassium acetate, potassium propionate, potassium thiocyanate, lithium bromide, lithium chloride, lithium perchlorate, lithium formate, lithium iodide, lithium nitrate, lithium acetate, lithium propionate, tetramethylguanidinium chloride, tetramethylguanidinium perchlorate, tetramethylammonium bromide, tetramethylammonium chloride, sodium bromide, sodium chloride, sodium perchlorate, sodium formate, sodium iodide, sodium nitrate, sodium acetate, sodium propionate, sodium thiocyanate, ammonium chloride, ammonium iodide, ammonium thiocyanate, tetrapentylammonium bromide, tetrapropylammonium bromide, tetrapropylammonium chloride, tetrapropylammonium iodide, rubidium perchlorate, rubidium iodide, zinc chloride, zinc iodide.
Contact Email
virginia.mazzini@anu.edu.au; vince.craig@anu.edu.au
Contact Address
Department of Applied Mathematics Research School of Physics and Engineering The Australian National University Canberra, ACT, 2601 AUSTRALIA
Principal Investigator
Virginia Mazzini
Supervisors
Prof. Vince Craig
Fields of Research
0306 - Physical Chemistry (incl. Structural); 030605 - Solution Chemistry
Keywords
activity coefficients; osmotic coefficients; nonaqueous solutions; salt solutions; nonaqueous electrolytes; nonaqueous solvents; Pitzer equations
Type of Research Activity
Pure basic research
Date Coverage
1965
2017
Date of data creation
2017
Year of data publication
2019
Creator(s) for Citation
Virginia
Mazzini
Vincent
Craig
Publisher for Citation
ANU Data Commons, The Australian National University
Publications
doi
10.1021/acscentsci.8b00348
Volcano Plots Emerge from a Sea of Nonaqueous Solvents: The Law of Matching Water Affinities Extends to All Solvents.
Mazzini, V. and Craig, V. S. J. ACS Central Science 2018 4 (8), 1056-1064, https://doi.org/10.1021/acscentsci.8b00348
handle
http://hdl.handle.net/1885/144595
Specific ion effects in non-aqueous solutions.
Mazzini, V. PhD Thesis. Department of Applied Mathematics, Research School of Physics and Engineering, The Australian National University. 2017, http://hdl.handle.net/1885/144595
Access Rights
Open Access allowed (see rights held in and over resource below).
Access Rights Type
Open
Rights held in and over the data
This data is provided and shared for non-commercial use. If you use the data for publications we ask that you reference the original manuscript and the DOI for this data set. If modifying and/or republishing the data we ask that you include the original header material without deletions. Creative Commons Licence CC BY-NC-SA is assigned to this data. Details of the licence can be found at http://creativecommons.org.au/licences
Licence Type
CC-BY-NC-SA - Attribution-NonCommercial-SharedAlike (Version 4.0)
Retention Period
Indefinitely
Extent or Quantity
1
Data Size
817 KB
Data Management Plan
No
Status: Published
Published to:
  • Australian National University
  • Australian National Data Service
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